The resolution, which expresses the Security Council's intention to impose sanctions if the Syrian government does not allow unrestricted aid deliveries to civilians caught in the fighting, was circulated among the 15 council members yesterday.
Western countries made clear they had no intention of dropping the proposal despite Russia's vow to block it a day earlier.
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Obama said Secretary of State John Kerry and others have "delivered a very direct message" pressuring the Russians to drop their opposition. He said "it is not just the Syrians that are responsible" for the plight of civilians but "the Russians, as well, if they are blocking this kind of resolution."
Hollande made clear France was determined to move forward with the resolution.
"How you can object to humanitarian corridors? Why would you prevent the vote of a resolution if, in good faith, it is all about saving human lives?" he said.
In Moscow, Russian Foreign Minister Sergey Lavrov said the text is a "one-sided" effort to blame the Syrian government, which Moscow supports, for holding up aid.
Still, Russian Ambassador Vitaly Churkin attended a Security Council meeting yesterday to discuss the text and told reporters later that it was "a good exchange of the challenges of the humanitarian situation in Syria."
A day earlier, both Churkin and China's ambassador were no-shows at a meeting with supporters of the draft resolution, and the Russian ambassador made clear his country would veto it if it were put to a vote. China sent its deputy ambassador to yesterday's meeting.
Russia and China have blocked three previous Western-backed resolutions that would have pressured President Bashar Assad to end the now three-year-old civil war.
The divided Security Council did come together in October to approve a presidential statement appealing for immediate access to all areas of Syria to deliver aid. Western and Arab countries want to go a step further with a legally binding resolution.
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