The extension of the tenuous truce in Homs came as around 450 civilians were given safe passage out of the war-ravaged city, according to Syria's Red Crescent, bringing the total number allowed out since Friday to some 1,200.
The evacuation of civilians from neighbourhoods where they had been trapped for nearly 18 months was marred by violence over the weekend, with 14 people killed in shelling that threatened to derail the humanitarian mission.
In Geneva meanwhile, the warring sides blamed each other for escalating violence that has killed hundreds of people across the country in recent days, as they did throughout a previous round of talks in late January.
The Syrian opposition delegation warned it would not return for a third round if no progress was made in the current session.
"If there is no progress at all, I think it would be a waste of time to think about a third round," opposition spokesman Louay Safi told reporters yesterday.
Brahimi wrote that he hoped that "separate sessions can lead to some positive outcomes," and tried to nudge the teams towards discussion of how to stop the fighting and agree on a political transition.
Both sides said there would be a joint session today, with the opposition saying it would begin at 10:00 am (0900 GMT).
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