Opting to bowl, Virat Kohli was in for a shock as KKR's new opener Sunil Narine hammered Samuel Badree for 18 runs in the opening over, hitting three fours and a six.
The next over, Gambhir had some tough time against Mills before using the Englishman's pace to guide the ball over third-man boundary.
It was raining boundaries and sixes as KKR raced to 39 in three overs before Mills finally gave the breakthrough dismissing KKR skipper for 14 when the ball kissed Gambhir's bottom-hand thumb and went to the wicketkeeper.
Narine slammed six boundaries and one six before holing out at deep square leg off Stuart Binny in the last over of Power Play.
Kohli introduced his ace spinner Chahal in the eighth over as the Haryana leggie bowled his quota at one go and rattled KKR who managed just 20 runs from 10 to 15 overs.
An alert Chahal quickly altered his line seeing Yusuf Pathan (8) stepping out for his first wicket and had him stumped while in the 12th over he struck twice to remove Manish Pandey (15) and Colin de Grandhomme (0).
Left-arm spinner Negi took wickets of Nathan Coulter Nile (2) and Suryakumar Yadav (15) in successive balls in the 18th over while Sreenath Aravind cleaned up Kuldeep Yadav (4) to bowl KKR out in 19.3 overs.
This is for the first time KKR were bowled out by RCB who would be sniffing a second win in a row, as it's a big ask for Gautam Gambhir to defend the modest total.
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