The accident took place at around 9.30 PM yesterday on Bhiwandi-Nashik road at Diva village in Thane district.
The car driver lost control over the wheels, as a result the vehicle hit the road divider, broke it and came on the other side where it collided with a tempo.
The vehicle was on way to Thane from Nashik. The car occupants were from Bhandup in Mumbai.
The deceased have been identified as - Vasant Kedar, Sachin Kedar, Amit Kedar and Sunita Kedar.
The Narpoli police registered a case under relevant IPC sections, including 304A (causing death by negligence) and 279 (rash driving or riding on a public way), police added.
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