The huge sweep of businesses, property and bank accounts "represents, in total value, one of the biggest seizures ever made", the anti-mafia department (DIA) said.
Authorities said the syndicate cultivated ties with the Italian anti-mafia movement in an effort to hide its activities from police.
"They struck upon the idea of developing ties with anti-racketeering groups in an attempt to make themselves look innocent while being targeted by criminal probes," Colonel Riccardo Sciuto of the DIA told a press conference.
In total 33 companies -- mostly in the cement business -- 700 houses, villas and buildings, as well as 40 bank accounts and 40 vehicles were seized.
The haul belonged to Carmelo Virga, 66, his brothers Vincenzo, 78, and 71-year-old Francesco, and their sisters Anna, 76, and Rosa, 68. While all came from modest backgrounds working in agriculture or as homemakers, they became very rich.
Authorities said bid rigging was one of their key enterprises.
The family "succeeded over time in developing and imposing their group of companies, by using the method known as 'Siino', which consists of organising cartels of entrepreneurs with a view to the 'directed' bidding for public tenders.
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