Foreign Minister Mohamed Abdelaziz asked the UN Security Council to dispatch experts to train Libya's defence and police forces to ensure they can protect oil fields, airports and other vital sites.
The call came amid a surge of violence in the country with clashes between rival militias sparking fears of all-out civil war.
Tripoli's mayor and leaders of battling militia said overnight that a truce had been agreed and that control of the international airport would be handed over to neutral forces.
Mokhtar Lakhdar, a commander for the Zintan forces, told AFP that a truce had been agreed under the authority of the city's government council.
Dozens of rockets have been fired at the airport, badly damaging planes as well as the main terminal, but Lakhdar confirmed this had halted last night.
Ex-rebel fighters from Zintan and Misrata, east of Tripoli, both played a key role in the NATO-backed uprising that toppled dictator Moamer Kadhafi in 2011.
Ahmed Hadeia, a spokesman for the rival Misrata fighters, said the ceasefire was "only around the airport" and did not include other sites controlled by the Zintan forces.
Misrata leaders said in a statement read out yesterday on television that the fighting at the airport was a "battle of revolutionaries... Against followers of the old regime" of Kadhafi.
The clashes revived fears of the conflict spreading inside Tripoli itself, with official results still awaited from a June 25 election to the parliament previously dominated by Islamists.
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