Some two hundred protesters crossed a denuded no-man's land and lined up like guards at the edge of the 40-square kilometre (15 square mile) Hambach opencast coal mine, the biggest man-made hole in Europe.
Operated by German electricity producer RWE Power AG, the Hambach operation mines lgnite, a brownish, low-grade coal.
Its high carbon content makes it one of the most polluting of fossil fuels.
As dozens of police encircled a 30-storey high bucket- wheel excavator, the protesters unfurled banners reading, "Welcome to COP23", "Burn borders, not coal" and "Climate Justice".
"On the international stage, politicians and corporations present themselves as climate saviours, while a few miles away the climate is literally being burned," said Janna Aljets, spokesperson for climate justice group Ende Gelande.
So far, RWE have broken ground on about half of the area designated for mining, and dug to a depth of more than 300 metres (1,000 feet) below sea level. The company extracts 40 million tonnes of lignite every year, according to its website.
The site holds reserves estimated at 2.5 billion tonnes.
The world is today burning more coal than it ever has, with global demand increasing an average of four per cent between 2000 and 2013. Under current policies, growth in use is expected to taper off over the next five years, but not peak until about 2030.
At the same time, the UN said in a recent report that 80 to 90 per cent of known coal reserves would have to stay in the ground for global warming to be held at under two degrees Celsius (3.6 degrees Fahrenheit), the temperature target laid down by 2015 Paris climate treaty.
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