A judge yesterday ordered the five, who fled Spain earlier this week after being accused of rebellion and sedition, not to leave Belgium until their extradition case is heard.
It is the latest twist in the crisis unleashed by the Catalan separatists' push to break away from Spain, sending shock waves across Europe.
Puigdemont and his allies escaped to Belgium last Monday after Spain dismissed the Catalan executive and imposed direct rule on the semi-autonomous region following the declaration of independence by the parliament there last month.
A white van believed to be carrying Puigdemont raced out of the Belgian prosecutor's office around 15 hours later, AFP reporters witnessed.
"The request made this afternoon by the Brussels' Prosecutor's Office for the provisional release of all persons sought has been granted by the investigative judge," said the statement by the prosecutor's office shortly afterwards.
The next court hearing will be in the following 15 days. Belgium has up to 60 days to decide whether to send the Catalans back to Spain.
Puigdemont wrote on Twitter on Saturday that he and his colleagues -- Meritxell Serret, Antoni Comin, Lluis Puig and Clara Ponsati -- would cooperate with the Belgian authorities.
Spain issued European arrest warrants on Friday after Puigdemont and his allies ignored a summons to appear before a judge on allegations linked to the move to declare Catalonia an independent republic.
Puigdemont, 54, insists that Catalonia earned the right to declare independence following a banned referendum last month and has described his detained colleagues as "political prisoners".
Yesterday, protesters in Catalan cities took to the streets to demand their release.
In Barcelona, city police said about 350 people gathered on the central University Square, shouting "Freedom" and carrying posters that read "Freedom for political prisoners".
Others stuck posters demanding their release on walls throughout the city.
The judge could "refuse to hand over Puigdemont if there is a proven serious risk to his fundamental rights," said Anne Weyembergh, president of the Institute of European Studies at the Free University of Brussels.
She said the court would need to see evidence of criminal offences before executing the warrant.
But cases of refusal are rare, according to several lawyers interviewed by AFP.
Puigdemont, who still describes himself as Catalonia's "president," has also said he is willing to run as a candidate in the December 21 regional election called by Prime Minister Mariano Rajoy to "restore normality" to Catalonia.
She said the conservative, pro-independence party was looking to put together a "big united list", a day after Puigdemont himself called for separatists to unite in the election.
During the last regional election in September 2015, Puigdemont's PDeCAT and the leftwing ERC party joined for a "Together for Yes" coalition in Catalonia, a region of 7.5 million people.
With the help of the separatist far-left CUP party, they held an absolute majority in the 135-seat Catalan parliament, which was swiftly dissolved by Madrid under a never-used constitutional move after the October 27 independence proclamation.
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