Sania and her Chinese Taipei partner Su-Wei Hsieh, who are seeded second, defeated the Argentine-Swiss combine of Maria Irigoyen and Romina Oprandi 6-2 6-0 in just 48 minutes to advance.
The Indo-Taipei team will now be up against the Canadian-Polish pair of Gabriela Dabrowski and Alicja Rosolska.
In the men's doubles event, 10th seeded Paes and his South African partner Raven Klaasen edged past the American duo of Scott Lipsky and Rajeev Ram 6-4 7-6 (6) to enter the second round.
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