The incident happened this afternoon at Sukholi, Deulwadi, under the jurisdiction of Khed police station.
Mahadeo Shivram Chalke (65) suffered a cardiac arrest while standing in a queue for Zilla Parishad election with his son and daughter-in-law.
"He was taken to a private hospital where he was declared dead," said senior police inspector Anil Gambhir.
Chalke was under treatment for heart ailments for the last few months, Gambhir added.
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