With the win, India levelled the series 1-1 and kept their hope alive to clinch the series. The third and deciding match will be played at the same venue on Friday.
Shikha, who earlier hauled three South African wickets, put on a match-winning 89-run stand for the fourth wicket with Harmanpreet Kaur (42 not out off 61 balls with four boundaries), to help India post 187 for four in 44.4 overs.
Shikha, who cracked her maiden ODI half century, was dismissed for 59 off 56 balls when she was caught by Aakash Rawat off Marizanne Kapp.
Shikha, the Goan girl, raced to her half century, smashing eight boundaries and a six along the way.
India started the run chase rather sedately with Poonam Raut and Smriti Mandhana, accumulating 37 runs in 14 overs, before the later offered a catch to Sunette Loubser off Dane Van Niekerk for 16 off 42 balls.
Poonam was looking good, defending and attacking the balls according to the merit of the ball, was removed leg before wicket by Lizelle Lee after she scored 47 off 77 balls with eight boundaries.
South African bowlers - Kapp, Niekerk, Loubser and Lee - did not have much to offer for scorers as they took one wicket each among themselves.
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