In 2014, some 866,000 people applied for asylum in such countries, marking a 45-per cent jump from a year earlier and a 22-year high, the UN refugee agency said.
The surge is linked to the spiralling conflicts in Syria and Iraq, which have created "the worst humanitarian crisis of our era," spokeswoman Melissa Fleming told reporters.
As a sign of the crisis, the number of asylum applications last year was the second highest on record, coming very close to the all-time-high of the about 900,000 requests made in 1992, at the beginning of the conflict in Bosnia and Herzegovina, UNHCR said.
Last year, 150,000 Syrians applied for asylum in industrialised countries, marking a 166-per cent hike from 2013 and accounting for a fifth of all asylum claims, the UNHCR report said.
As the violence in Syria has spilled over into neighbouring Iraq with the ruthless Islamic State jihadist group, Iraqis too have been leaving in droves.
Last year they accounted for 68,700 asylum applications to wealthy nations - almost double the number a year earlier - while Afghans made up the third largest group, with almost 60,000 applications.
"What we are seeing now is a trend towards ... A feeling like this war is never" going to end, Fleming said, pointing out that many had set their sights on Europe.
This trend explains the sharp increase in Syrians attempting to make the perilous journey across the Mediterranean, she said, urging European countries to respond as generously to the current crisis as they did during the Balkan war.
But the burden is spread far from evenly among the 44 industrialised countries included in the report.
The top five receiving countries - Germany, the United States, Turkey, Sweden and Italy - accounted for 60 per cent of all new applications last year, UNHCR said.
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