May, 60, is expected to sail through with the support of the Democratic Unionist Party (DUP) voting with the Conservatives as part of a "confidence and supply" arrangement after the Tories lost their overall majority in the June 8 snap general election.
Votes on the Queen's Speech establish whether a government commands the confidence of the House of Commons.
If the Conservatives were to lose, it could trigger another general election and therefore the DUP support will be crucial to ensure the vote goes through.
Today,Labour leader Jeremy Corbyn is hoping to highlight apparent divisions within the Conservative ranks over whether to put jobs and the economy first in Brexit talks.
It plans to table an amendment criticising what it says is the absence of measures to "reverse falling living standards" such as action on energy bills and wages.
Corbyn claims that May has no mandate for continued austerity measures after she failed to win an outright majority at the last election.
May faces a hectic schedule today as she will be rushing back from a summit in Germany in time for the parliamentary proceedings in the UK.
In Berlin, May joins German Chancellor Angela Merkel, French President Emmanuel Macron and other European leaders to discuss plans for the G20 summit in Hamburg next week and how to put pressure on US President Donald Trump over his refusal to sign up to the Paris Agreement on climate change, as well as the stalled trade deal between the US and the European Union.
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