Hagel said he had informed Kiev that President Barack Obama "has approved additional non-lethal military assistance for health and welfare items and other supplies."
"These supplies include medical supplies, helmets, sleeping mats and water purification units for Ukraine's armed forces, as well as shelters, small power generators and hand fuel pumps for Ukraine's State Border Guard Service," the Pentagon chief said.
"The United States continues to stand with Ukraine," Hagel told reporters at a joint press conference with Poland's visiting Defense Minister Tomasz Siemoniak.
The items to be sent to Ukraine did not appear to include bullet-proof vests, night vision goggles or other items that could be used during combat.
Washington sent some 300,000 food rations to Kiev in late March.
"The United States will continue to review additional support that we can provide to Ukraine," Hagel said.
McCain, who lost the White House election to Obama in 2008, decried steps taken by the US and European Union thus far as "almost laughable" during a visit to Lithuania yesterday.
He and other lawmakers have called on Washington to provide military assistance to Ukraine, including light arms and anti-aircraft defenses.
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