Tsvangirai, who has dismissed the July 31 election as a "farce" after it extended Mugabe's 33-year rule by another five years, appeared to reject any such talks.
"After stealing the vote, they don't even know where to start."
"They are now asking 'where is Tsvangirai, so that we can talk?' Talk about what?" he said at the burial of a party activist who died last week.
But Mugabe's ZANU-PF party denied ever approaching him for talks.
Mugabe was declared the winner with 61 per cent of the ballots, against Tsvangirai's 34 per cent.
Tsvangirai, who took part in a power-sharing government with Mugabe over the past four years, has said he will only settle for a vote re-run.
He has filed a petition at the country's top court which he vowed will expose "glaring evidence of the stolen vote".
Added to the crushing defeat at the polls, he said the party had suffered a double blow following the death of party activist Rebecca Mafikeni in a state hospital where she was transferred from remand prison.
Mafikeni who was 29 at the time of her death, was among 29 activists from Tsvangirai's Movement for Democratic Change (MDC) party detained since May 2011 on allegations of killing an officer as riot police broke up an MDC rally. She had been awaiting trial.
"Rebecca's death is an indictment of our prison system, an indictment of our justice system." Tsvangirai said.
He said the outcome of his court challenge against Mugabe's win was predictable but urged his supporters to remain calm.
"We should not set our own house on fire," he said.
Mugabe on Monday vowed never to let go of his victory telling Tsvangirai and his party to "go hang".
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