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All 32 men and women will be gearing up to book a quarter-final berth at Wimbledon singles draw on Monday following a day of rest.
While seven-time champion Roger Federer will take on 20th seed Roberto Bautista Agut of Spain, world number one Novak Djokovic faces South Africa's Kevin Anderson, the BBC reported.
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Meanwhile, Britain number one Andy Murray will square off against 6ft 11in Croatian Ivo Karlovic in his fourth-round match.
In the women's single, the Williams sisters (Serena and Venus) will face each other for the first time in six years.
Meanwhile, French Open champion Stanislas Wawrinka will meet 16th seed David Goffin and Maria Sharapova takes on Kazakhstan's Zarina Diyas.
