Cameron will be here on a day-long visit, his third in two years, on his way to Colombo to attend the Commonwealth Heads of Government Meeting (CHOGM) on November 15-16.
The British Prime Minister will hold talks with Singh on number of crucial bilateral, regional and international issues.
Both the leaders are likely to deliberate on boosting cooperation in trade and investment besides enhancing ties in areas of mutual interest.
Vodafone, a British company, is facing tax liability of over Rs 11,217 crore for purchase of Hong Kong-based Hutchison Whampoa's stake in Indian telecom business Hutchison Essar in 2007.
The Government has agreed to resolve the issue amicably but there has been no significant development in the case so far.
During his visit to India in February, both India and the UK had decided to start negotiations on a civil nuclear pact to facilitate entry of British companies into emerging Indian atomic power sector besides agreeing to explore ways to enhance cooperation in diverse sectors.
There are about 700 Indian companies which have operations in the UK out of which over 70 are listed on London Stock Exchange.
Cameron will arrive here tonight. After holding talks with Singh, he will leave for Kolkata where he will meet West Bengal Chief Minister Mamata Banerjee.
He will also visit the Indian Museum to see restoration work and interact with an NGO.
Cameron's visit to India comes over a week after UK announced its decision to scrap the controversial 3,000-pound visa bond scheme for some "high risk" overseas visitors to the the country including those from India which was scheduled to be implemented on a pilot basis this month.
India, which had raised the matter with the UK Government, welcomed the decision.
