The Hollywood A-listers have filmed guest segments with Jeremy and his fellow former "Top Gear" hosts Richard Hammond and James May, reported Contactmusic.
The new show, which will air on Amazon's streaming service, Prime, later this year, marks the return of the presenters to broadcasting after Jeremy's controversial axing from "Top Gear" last year.
"All the early signs suggest The Grand Tour will have a much bigger pulling power than Top Gear," a source said.
"Matt and Charlize are just two of the names involved. More big stars will follow. Top Gear's influence and power has clearly waned without Jeremy at the helm."
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