They were among at least 76 people to die when their boat went down yesterday off the western Libyan port of Zuwara, Red Crescent spokesman Mohamad al-Misrati told AFP.
Up to 198 other people were saved, including many of Arab and African origin, but dozens of others are still missing at sea, he said.
At a police station near Zuwara, Hamza sat on the ground next to his brother among those rescued.
"It was a wooden boat with about 350 people on board, including my father, my mother, my little sister (aged 11), my older sister (27) and my brother (16).
"After an hour and a half, the boat started shaking, then water started to leak in, and very fast we found ourselves in the sea," he said, a hand on his forehead and gaze cast to the ground.
"The boat shattered into pieces of wood. My mother and I grabbed on to one and I saw my brother and little sister by my side.
"My little sister, someone climbed on her back and pushed her down. When I saw her for the last time, she was underwater with him on top of her."
"My mother and I spent nine hours in the water, holding on to a bit of wood. I kept telling her everything would be okay. But a quarter of an hour before the rescue team arrived, she passed away," he said.
"She died in my arms. I asked the man to let me take her body with me, but he refused. My mother is dead. My little sister is dead."
One of those rescued said he and his two friends had each paid 2,200 dinars (about USD 1,600) to get on the ill-fated boat.
People smugglers have taken advantage of the chaos gripping Libya since the 2011 uprising to step up their lucrative business.
But the crossing to Europe is treacherous, and more than 2,500 people have died this year alone, according to the UN refugee agency.
This figure excludes those who died when Hamza and his family's boat sank.
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