Video footage on Ukrainian television showed shocking scenes today of protesters being cut down by gunfire, lying on the pavement as comrades rushed to their aid.
Trying to protect themselves with shields, teams of protesters carried bodies away on sheets of plastic or planks of wood.
One of the wounded, volunteer medic Olesya Zhukovskaya, sent out a brief Twitter message, "I'm dying", after being shot in the neck. Dr Oleh Musiy, the medical coordinator for the protesters, said she was in serious condition after being operated on.
In Brussels, the 28-nation European Union decided in an emergency meeting today to impose sanctions against those behind the violence in Ukraine. The US is considering whether to join the EU sanctions.
Protesters were also seen leading policemen with their hands held high around the sprawling protest camp in central Kiev.
Ukraine's Interior ministry says 67 police were captured in all, it was not clear how. An opposition lawmaker said they were being held in Kiev's occupied city hall.
Parts of the country, mostly in its western cities, are in open revolt against Yanukovych's central government, while many in eastern Ukraine back the president and favour strong ties with Russia, their former Soviet ruler.
Protesters across the country are also upset over corruption in Ukraine, the lack of democratic rights and the country's ailing economy, which just barely avoided bankruptcy with a USD 15 billion loan from Russia.
Today was the deadliest day yet at the sprawling protest camp on Kiev's Independence Square, also called the Maidan.
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