The promise was published on the front page of leading Scottish newspaper the Daily Record and was printed to look like a yellowed scroll with the signatures and faces of the three party leaders.
Published under the headline "The Vow", the promise by Conservative Prime Minister David Cameron, opposition Labour party leader Ed Miliband, and Liberal Democrat Deputy Prime Minister Nick Clegg re-iterates previous commitments.
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"People want to see change. A 'No' vote will deliver faster, safer and better change than separation."
Pro-independence Scottish First Minister Alex Salmond immediately hit back, calling it a "last minute desperate offer of nothing".
He said on BBC Radio Scotland that it was "not going to dissuade people in Scotland from the huge opportunity of taking Scotland's future into Scotland's hands this coming Thursday".
Polls have showed a late surge in support for independence, putting the outcome on a knife edge, after the "No" led for many months.
The "No" is still marginally ahead in most of the polls, more of which were due to be published on Wednesday on the final day of campaigning.
"It's clear that project panic is willing to say anything in the last few days of the campaign to try to halt the 'Yes' momentum," a spokesman for the pro-independence campaign said.
"The reality is that the only way to guarantee Scotland gets all the powers we need... Is with a 'Yes' vote on Thursday."
Opposition Labour party leader Ed Miliband meanwhile condemned what he called "ugly" tactics being used by "Yes" supporters after he was heckled during a visit to an Edinburgh shopping centre.
"I think debates should be conducted in a civilised way. I think it's very, very important. But I understand that passions run high," he told reporters.
In Edinburgh, 50-year-old Heather Wright said she was confident that Scots would vote for independence -- although she acknowledged that many people were still undecided and it would be "very close".
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