The 88-year-old chain, which sells clothing, food and homeware, has failed to keep pace with traditional rivals such as Marks & Spencer and online giants like Amazon, resulting in a major loss of market share.
"Philip Duffy and Benjamin Wiles, managing directors of Duff & Phelps (the administrators) have today announced the orderly wind down of the BHS business," read a statement.
The company's 163 stores will enter "close-down sale mode" over the coming weeks in an "orderly wind-down" of the business.
"Despite the considerable efforts of the administrators and BHS senior management it has not been possible to agree a sale of the business," the statement added.
"Although multiple offers were received, none were able to complete a deal due the working capital required to secure the future of the company.
"Our thoughts today are with the employees. We thank them for their professionalism and hard work. We would also like to thank the great British public for helping us in our efforts to save BHS resulting in several weeks of significant sales."
However, Duff & Phelps was unable to turn around the fortunes of the faltering retail giant.
"The British high street is changing and in these turbulent times for retailers, BHS has fallen as another victim of the seismic shifts we are seeing," said Philip Duffy, managing director of Duff & Phelps.
"The tireless work and goodwill of the existing management team and employees of BHS with the support of my team were not enough to change the fortunes of the company."
Last year however, BHS pulled in just 8.2 per cent of clothing shoppers, handing it a 1.4-per cent share of the sector, according to Conlumino.
Starting in 1928 with a chain in London, BHS has since grown to stand at 163 stores and 74 franchise operations across 18 countries.
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