President Bashar al-Assad's forces have seized two-thirds of the former rebel bastion in east Aleppo since they began an operation to recapture all of the battered second city in mid-November.
The rapid gains for regime forces have left opposition fighters reeling and today Russian Foreign Minister Sergei Lavrov said talks would be held on a rebel evacuation.
"During the Russian-American consultations the concrete route and timeframe for the withdrawal of all fighters from eastern Aleppo will be agreed upon," Lavrov said, adding that the discussions in Geneva would likely start on Tuesday or Wednesday.
But rebel groups swiftly rejected any talk of an evacuation.
Yasser al-Youssef of the Nureddine al-Zinki faction, a leading rebel group in Aleppo, described any such proposal as "unacceptable".
"It is for the Russians to leave," he told AFP.
Moscow is a close ally of Assad's government, and launched a military intervention in support of Damascus last year.
Government troops have also been bolstered by Iranian forces, fighters from Lebanon's Shiite Hezbollah movement and Shiite fighters from other countries.
"The revolutionaries will not leave Aleppo and will fight the Russian and Iranian occupation until the last drop of blood," said Abu Abdel Rahman al-Hamawi of the Army of Islam, another smaller rebel group active in Aleppo.
In many instances, they have reached deals with the government after months of army siege and fierce fighting, agreeing to lay down their arms in return for safe passage to rebel territory elsewhere.
Among the most well-known evacuations was the 2014 exit of rebels from the Old City of Homs after a two-year government siege.
But if Washington and Moscow were to agree a deal for a rebel evacuation from Aleppo, it would mark the first time that the two powers, which back opposing sides in the war, have negotiated the withdrawal of opposition forces.
The UN's Syria envoy Staffan de Mistura in October put the number at 8,000 rebels, saying around 900 of them belonged to Al-Qaeda's former affiliate, now known as Fateh al-Sham.
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